000			03784nam a22005295i 4500
001			978-3-540-37210-3
003			DE-He213
005			20161121231141.0
007			cr nn 008mamaa
008			100301s2007 gw | s |||| 0|eng d
020			_a9783540372103 _9978-3-540-37210-3
024	7		_a10.1007/11603818 _2doi
050		4	_aQD410-412.5
072		7	_aPNND _2bicssc
072		7	_aSCI013040 _2bisacsh
082	0	4	_a547.05 _223
245	1	0	_aOrganometallic Oxidation Catalysis _h[electronic resource] / _cedited by Franc Meyer, Christian Limberg.
246	3		_aWith contributions by numerous experts
264		1	_aBerlin, Heidelberg : _bSpringer Berlin Heidelberg, _c2007.
300			_aXI, 253 p. _bonline resource.
336			_atext _btxt _2rdacontent
337			_acomputer _bc _2rdamedia
338			_aonline resource _bcr _2rdacarrier
347			_atext file _bPDF _2rda
490	1		_aTopics in Organometallic Chemistry, _x1436-6002 ; _v22
505	0		_aIntrinsic Mechanisms of Oxidation Reactions as Revealed by Gas-Phase Experiments -- Dioxygen Activation by Organometallics of Early Transition Metals -- Organorhenium and Organomolybdenum Oxides as Heterogenised Catalysts -- The SOHIO Process as an Inspiration for Molecular Organometallic Chemistry -- Catalysis and Organometallic Chemistry of Rhodium and Iridium in the Oxidation of Organic Substrates -- The Role of NHC Ligands in Oxidation Catalysis -- Palladium-Catalyzed Oxidation Reactions: Comparison of Benzoquinone and Molecular Oxygen as Stoichiometric Oxidants -- Homogeneous Copper-Catalyzed Oxidations.
520			_aEighty per cent of all compounds produced in the chemical and pharmaceutical industries require at least one essential catalytic step during their synthesis. At the same time the use of hydrocarbons as a feed-stock for commodity and fine chemicals typically requires an oxidation step, which is usually mediated by a transition metal compound. Consequently oxidation catalysis is a major research field in chemistry, both in academia and in industry. In many such processes, species with metal-carbon bonds are formed as key intermediates, and these processes represent the primary focus of this volume. An important aspect covered by some of the expert contributors is the use of organic ligands - and thus organometallic complex metal fragments - to achieve efficient oxidation catalysis. It has not been self-evident that organometallic complexes can survive the conditions necessary for polar oxygen-transfer reactions, but research over the last decade concerning oxo and peroxo complexes functionalized by organic ligands has clearly shown that relatively non-polar M-C bonds can be quite stable in the presence of oxidants and protic media, and that they may even be essential for the favourable activity and life-time of a catalyst. Also considered in this context is the oxidation chemistry of basic organometallic species in the gas phase, as this may reveal fundamental characteristics inherent to oxidation catalysts.
650		0	_aChemistry.
650		0	_aInorganic chemistry.
650		0	_aOrganometallic chemistry.
650		0	_aMedicinal chemistry.
650		0	_aCatalysis.
650	1	4	_aChemistry.
650	2	4	_aOrganometallic Chemistry.
650	2	4	_aCatalysis.
650	2	4	_aInorganic Chemistry.
650	2	4	_aMedicinal Chemistry.
700	1		_aMeyer, Franc. _eeditor.
700	1		_aLimberg, Christian. _eeditor.
710	2		_aSpringerLink (Online service)
773	0		_tSpringer eBooks
776	0	8	_iPrinted edition: _z9783540372097
830		0	_aTopics in Organometallic Chemistry, _x1436-6002 ; _v22
856	4	0	_uhttp://dx.doi.org/10.1007/11603818
912			_aZDB-2-CMS
950			_aChemistry and Materials Science (Springer-11644)
999			_c509318 _d509318