000 03973nam a22005175i 4500
001 978-3-540-36930-1
003 DE-He213
005 20161121231141.0
007 cr nn 008mamaa
008 140203s2007 gw | s |||| 0|eng d
020 _a9783540369301
_9978-3-540-36930-1
024 7 _a10.1007/978-3-540-36930-1
_2doi
050 4 _aQD410-412.5
072 7 _aPNND
_2bicssc
072 7 _aSCI013040
_2bisacsh
082 0 4 _a547.05
_223
100 1 _aGlorius, Frank.
_eauthor.
245 1 0 _aN-Heterocyclic Carbenes in Transition Metal Catalysis
_h[electronic resource] /
_cby Frank Glorius.
246 3 _aWith contributions by numerous experts
264 1 _aBerlin, Heidelberg :
_bSpringer Berlin Heidelberg :
_bImprint: Springer,
_c2007.
300 _aXII, 232 p.
_bonline resource.
336 _atext
_btxt
_2rdacontent
337 _acomputer
_bc
_2rdamedia
338 _aonline resource
_bcr
_2rdacarrier
347 _atext file
_bPDF
_2rda
490 1 _aTopics in Organometallic Chemistry,
_x1436-6002 ;
_v21
505 0 _aN-Heterocyclic Carbenes in Catalysis—An Introduction -- N-Heterocyclic Carbenes in Catalysis—An Introduction -- N-Heterocyclic Carbenes as Ligands for High-Oxidation-State Metal Complexes and Oxidation Catalysis -- N-Heterocyclic Carbenes as Ligands for High-Oxidation-State Metal Complexes and Oxidation Catalysis -- Palladium-catalyzed Reactions Using NHC Ligands -- Palladium-catalyzed Reactions Using NHC Ligands -- Routes to N-Heterocyclic Carbene Complexes -- Routes to N-Heterocyclic Carbene Complexes -- Chiral N-Heterocyclic Carbenes as Stereodirecting Ligands in Asymmetric Catalysis -- Chiral N-Heterocyclic Carbenes as Stereodirecting Ligands in Asymmetric Catalysis -- Transition Metal-Catalyzed Reactions Using N-Heterocyclic Carbene Ligands (Besides Pd- and Ru-Catalyzed Reactions) -- Transition Metal-Catalyzed Reactions Using N-Heterocyclic Carbene Ligands (Besides Pd- and Ru-Catalyzed Reactions) -- N-Heterocyclic Carbenes as Ligands for Olefin Metathesis Catalysts -- N-Heterocyclic Carbenes as Ligands for Olefin Metathesis Catalysts.
520 _aIt was only in the early 1990s that carbenes with the carbene carbon being incorporated in a nitrogen containing heterocycle (N-heterocyclic carbenes or NHCs) were found to be stable enough to be isolated. Since the first report on the application of NHCs as ligands in transition metal catalysis in 1995, NHC have found numerous applications and have been established as a versatile and indispensable class of ligands. For many reactions like metathesis or cross-coupling reactions NHCs have often become the ligands of choice, allowing otherwise difficult transformations. In this book leading experts have surveyed major areas of application of NHC metal complexes in catalysis. The authors have placed a special focus on nickel- and palladium-catalyzed reactions, on applications in metathesis reactions, on oxidation reactions and on the use of chiral NHC-based catalysts. This compilation is rounded out by an introductory chapter and a chapter dealing with synthetic routes to NHC metal complexes. The use of NHC as ligands in catalysis has reached a certain level of maturity and this book allows the reader to get a balanced view of this increasingly important ligand class.
650 0 _aChemistry.
650 0 _aInorganic chemistry.
650 0 _aOrganometallic chemistry.
650 0 _aMedicinal chemistry.
650 0 _aCatalysis.
650 1 4 _aChemistry.
650 2 4 _aOrganometallic Chemistry.
650 2 4 _aCatalysis.
650 2 4 _aInorganic Chemistry.
650 2 4 _aMedicinal Chemistry.
710 2 _aSpringerLink (Online service)
773 0 _tSpringer eBooks
776 0 8 _iPrinted edition:
_z9783540369295
830 0 _aTopics in Organometallic Chemistry,
_x1436-6002 ;
_v21
856 4 0 _uhttp://dx.doi.org/10.1007/978-3-540-36930-1
912 _aZDB-2-CMS
950 _aChemistry and Materials Science (Springer-11644)
999 _c509317
_d509317