000 03738nam a22005055i 4500
001 978-3-540-31444-8
003 DE-He213
005 20161121231103.0
007 cr nn 008mamaa
008 100806s2005 gw | s |||| 0|eng d
020 _a9783540314448
_9978-3-540-31444-8
024 7 _a10.1007/b94252
_2doi
050 4 _aQD410-412.5
072 7 _aPNND
_2bicssc
072 7 _aSCI013040
_2bisacsh
082 0 4 _a547.05
_223
245 1 0 _aTheoretical Aspects of Transition Metal Catalysis
_h[electronic resource] :
_b-/- /
_cedited by Gernot Frenking.
264 1 _aBerlin, Heidelberg :
_bSpringer Berlin Heidelberg,
_c2005.
300 _aXII, 266 p.
_bonline resource.
336 _atext
_btxt
_2rdacontent
337 _acomputer
_bc
_2rdamedia
338 _aonline resource
_bcr
_2rdacarrier
347 _atext file
_bPDF
_2rda
490 1 _aTopics in Organometallic Chemistry,
_x1436-6002 ;
_v12
505 0 _aD.G. Musaev, K. Morokuma: Transition Metal Catalyzed s-Bond Activation and Formation Reactions -- S. Sakaki: Theoretical Studies of C-H s-Bond Activation and Related Reactions by Transition-Metal Complexes -- G. Drudis-Solé, G. Ujaque, F. Maseras and A. Lledós: Enantioselectivity in the Dihydroxylation of Alkenes by Osmium Complexes -- D.V. Deubel, C. Loschen and G. Frenking: Organometallacycles as Intermediates in Oxygen-Transfer Reactions. Reality or Fiction? -- A. Michalak, T. Ziegler: Late Transition Metals as Homo- and Co-Polymerization Catalysts -- S. Tobisch: Co-Oligomerization of 1,3-Butadiene and Ethylene Promoted by Zerovalent ‘Bare’Nickel Complexes -- V. Staemmler: The Cluster Approach for the Adsorption of Small Molecules on Oxide Surfaces.
520 _aTransition metal catalysis belongs to the most important chemical research areas because a ubiquitous number of chemical reactions are catalyzed by transition metal compounds. Many efforts are being made by industry and academia to find new and more efficient catalysts for chemical processes. Transition metals play a prominent role in catalytic research because they have been proven to show an enormous diversity in lowering the activation barrier for chemical reactions. For many years, the search for new catalysts was carried out by trial and error, which was costly and time consuming. The understanding of the mechanism of the catalytic process is often not very advanced because it is difficult to study the elementary steps of the catalysis with experimental techniques. The development of modern quantum chemical methods for calculating possible intermediates and transition states was a breakthrough in gaining an understanding of the reaction pathways of transition metal catalyzed reactions. This volume, organized into eight chapters written by leading scientists in the field, illustrates the progress made during the last decade. The reader will obtain a deep insight into the present state of quantum chemical research in transition metal catalysis.
650 0 _aChemistry.
650 0 _aInorganic chemistry.
650 0 _aOrganometallic chemistry.
650 0 _aChemistry, Physical and theoretical.
650 0 _aMedicinal chemistry.
650 1 4 _aChemistry.
650 2 4 _aOrganometallic Chemistry.
650 2 4 _aTheoretical and Computational Chemistry.
650 2 4 _aMedicinal Chemistry.
650 2 4 _aInorganic Chemistry.
700 1 _aFrenking, Gernot.
_eeditor.
710 2 _aSpringerLink (Online service)
773 0 _tSpringer eBooks
776 0 8 _iPrinted edition:
_z9783540235101
830 0 _aTopics in Organometallic Chemistry,
_x1436-6002 ;
_v12
856 4 0 _uhttp://dx.doi.org/10.1007/b94252
912 _aZDB-2-CMS
950 _aChemistry and Materials Science (Springer-11644)
999 _c508352
_d508352