000 03480nam a22004815i 4500
001 978-0-387-25972-7
003 DE-He213
005 20161121231055.0
007 cr nn 008mamaa
008 110416s2005 xxu| s |||| 0|eng d
020 _a9780387259727
_9978-0-387-25972-7
024 7 _a10.1007/b136380
_2doi
050 4 _aQD505
072 7 _aPNRD
_2bicssc
072 7 _aSCI013060
_2bisacsh
082 0 4 _a541.395
_223
100 1 _aVannice, M. Albert.
_eauthor.
245 1 0 _aKinetics of Catalytic Reactions
_h[electronic resource] /
_cby M. Albert Vannice.
264 1 _aBoston, MA :
_bSpringer US,
_c2005.
300 _aXX, 240 p.
_bonline resource.
336 _atext
_btxt
_2rdacontent
337 _acomputer
_bc
_2rdamedia
338 _aonline resource
_bcr
_2rdacarrier
347 _atext file
_bPDF
_2rda
505 0 _aDefinitions and Concepts -- Catalyst Characterization -- Acquisition and Evaluation of Reaction Rate Data -- Adsorption and Desorption Processes -- Kinetic Data Analysis and Evaluation of Model Parameters for Uniform (Ideal) Surfaces -- Modeling Reactions on Uniform (Ideal) Surfaces -- Modeling Reactions on Nonuniform (Nonideal) Surfaces -- Kinetics of Enzyme-Catalyzed Reactions.
520 _aThis textbook contains all the information needed for graduate students or industrial researchers to design kinetic experiments involving heterogeneous catalysts, to characterize these catalysts, to acquire valid rate data, to verify the absence of mass (and heat) transfer limitations, to propose reaction models, to derive rate expressions based on these models and, finally, to assess the consistency of these rate equations. Langmuir, Freundlich, and Temkin isotherms are derived and the former are used in Langmuir-Hinshelwood (and Hougen-Watson) models, as well as reaction sequences without a rate-determining step, to obtain rate expressions on uniform surfaces. In addition, rate equations based on non-uniform (Temkin-type) surfaces are examined as an alternative approach. The most recent technique to calculate heats of adsorption and activation barriers on metal surfaces, the BOC-MP approach, is discussed in detail. Methods to measure metal surface areas and crystallite sizes using x-ray diffraction, transmission electron microscopy and various chemisorption techniques are discussed. Different experimental techniques to determine the influence of mass transfer limitations, especially within the pores of a catalyst, are reviewed in detail, with a particular emphasis on liquid-phase reactions. Many illustrations of these and other topics are provided along with numerous problems and a Solutions Manual for instructors. This book will be applicable to any graduate course in chemical engineering, chemistry or materials science that involves kinetics of catalytic reactions, including those catalyzed by enzymes.
650 0 _aChemistry.
650 0 _aInorganic chemistry.
650 0 _aPhysical chemistry.
650 0 _aChemical engineering.
650 0 _aCatalysis.
650 1 4 _aChemistry.
650 2 4 _aCatalysis.
650 2 4 _aInorganic Chemistry.
650 2 4 _aPhysical Chemistry.
650 2 4 _aIndustrial Chemistry/Chemical Engineering.
710 2 _aSpringerLink (Online service)
773 0 _tSpringer eBooks
776 0 8 _iPrinted edition:
_z9780387246499
856 4 0 _uhttp://dx.doi.org/10.1007/b136380
912 _aZDB-2-CMS
950 _aChemistry and Materials Science (Springer-11644)
999 _c508174
_d508174